Synthesis of Elastomers with Metallocene Catalysts. Synthesis of Olefinic Elastomers with Metallocene Catalysts.

single-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate

in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...

Homogeneous and heterogeneous oligomerization reactions of olefins with unbridged metallocene catalysts

1-Pentene, respectively 1-hexene, were reacted with 13 homogeneous metallocene catalysts to give linear oligomerization products, predominantly dimers, with selectivities above 90%. The product distributions of the codimerization reactions of 1-pentene with 1-hexene reflected a binomial behaviour. Therefore, the ratio for dimers is 1:2:1 (C10:C11:C12) while the trimers (pentadecenes up to octad...

IN SITU SILICA SUPPORTED METALLOCENE CATALYSTS FOR ETHYLENE POLYMERIZATION

Bis(2-R-ind)ZrCl2 (R: H or phenyl) was supported on different types of silica by in situ impregnation method and used for ethylene polymerization. In this method, the step of catalyst loading on support was eliminated and common alkyl aluminum (triisobutylaluminum, TiBA) cocatalyst was used instead of expensive methyl aluminiumoxane (MAO) cocatalyst in the polymerization. The effect of surface ...

synthesis and characterization of epdm elastomers

a series of ethylene-propylene-2-ethylidenebicyclo [2.2.1] hept.5-ene terpolymers (epdm) have been prepared using a vocl3/al2et3cl3 catalyst under various al/v ratios and diene concentrations via solution polymerization and characterized by ftir, mooney viscosity (ml1+4,125oc), and thermal gravimetery analyzing. the polymerization yield was seen to increase with augmentation of the al/v ratio a...

Endowing aspecific, unbridged-metallocene propylene-polymerization catalysts with isospecificity: the unprecedented role of MAO.